Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition.
Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition.
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DOI：
10.1039/c5cc07073b
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发表时间：
2015-10
影响因子：
4.9
通讯作者：
Long-Fei Wang;Jiang-Zhen Qiu;Jun‐Liang Liu;Yan‐Cong Chen;J. Jia;J. Jover;E. Ruiz;M. Tong
中科院分区：
文献类型：
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作者：
Long-Fei Wang;Jiang-Zhen Qiu;Jun‐Liang Liu;Yan‐Cong Chen;J. Jia;J. Jover;E. Ruiz;M. Tong
The first example of phototunable SMMs has been reported. Upon UV irradiation, variations of the coordination sphere around Dy(III) ions actually affect the magnetic behaviour of the compound via [2+2] cycloaddition reaction, leading to a magnetic transformation from the SMM behaviour to a field-induced slow relaxation.
