Specific derivatization of lysozyme in aqueous solution with Re(CO)3(H2O)3+

Specific derivatization of lysozyme in aqueous solution with Re(CO)3(H2O)3+
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DOI:
10.1039/b923688k
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发表时间:
2010-01-01
影响因子:
4.9
通讯作者:
Rowlett, Roger S.
Rowlett, Roger S.
中科院分区:
化学2区
文献类型:
--
作者:
Binkley, Sarah L.;Ziegler, Christopher J.;Rowlett, Roger S.

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Re(CO)(3)(H2O)(3)(+)与鸡蛋溶菌酶在水溶液中反应生成单一共价加合物;单晶 X 射线衍射表明,铼三羰基阳离子以两种显着分布的旋转异构体构象与 His15 结合。
The reaction of Re(CO)(3)(H2O)(3)(+) with hen egg lysozyme in aqueous solution results in a single covalent adduct; single crystal X-ray diffraction shows that the rhenium tricarbonyl cation binds to His15 in two significantly populated rotamer conformations.