Rhodium-catalyzed asymmetric arylation of azomethine imines.
Rhodium-catalyzed asymmetric arylation of azomethine imines.
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DOI：
10.1021/ol101700v
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发表时间：
2010-08
期刊：
影响因子：
5.2
通讯作者：
R. Shintani;Ying‐Teck Soh;Tamio Hayashi
中科院分区：
文献类型：
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作者：
R. Shintani;Ying‐Teck Soh;Tamio Hayashi
已经描述了四芳基硼酸钠与偶氮甲碱亚胺的铑催化加成。通过使用手性二烯配体也实现了高效的不对称催化，得到具有高对映选择性的1-(二芳基甲基)吡唑烷-3-酮。
A rhodium-catalyzed addition of sodium tetraarylborates to azomethine imines has been described. Highly efficient asymmetric catalysis has also been achieved by employing a chiral diene ligand to give 1-(diarylmethyl)pyrazolidin-3-ones with high enantioselectivity.