Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes
Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes
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DOI：
10.1021/ja106809p
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发表时间：
2010-10-20
影响因子：
15
通讯作者：
Lam, Hon Wai
中科院分区：
文献类型：
--
作者：
Pattison, Graham;Piraux, Guillaume;Lam, Hon Wai
在铑配合物的存在下，含有一个新开发的手性二烯配体，烯烃活化的范围内的π-不足或π-过量的杂芳烃从事高对映选择性共轭加成与各种芳基硼酸。
In the presence of a rhodium complex containing a newly developed chiral diene ligand, alkenes activated by a range of pi-deficient or pi-excessive heteroarenes engage in highly enantioselective conjugate additions with various arylboronic acids.