New Method for the Fabrication of a Charge Transfer Complex by Photoirradiation
New Method for the Fabrication of a Charge Transfer Complex by Photoirradiation
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光照射制备电荷转移复合物的新方法
DOI：
10.1002/chem.201402644
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发表时间：
2014
期刊：
影响因子：
--
通讯作者：
Hiroyuki Hasegawa
中科院分区：
文献类型：
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作者：
Masaki Matsuda;Miki Nishi;Shoko Koga;Mika Fujishima;Norihisa Hoshino;Tomoyuki Akutagawa;Hiroyuki Hasegawa
提出了一种制备电荷转移配合物晶体的新方法。将TPP[Co（tbp）（CN）2]和TPP[Co（Pc）（CN）2]（tbp=四苯并卟啉，Pc=酞菁，TPP=四苯基膦）的溶液进行光照射，得到电荷转移络合物TPP[Co（tbp）（CN）2]2的分子导电晶体，其通过其中tbp中的光激发电子从tbp的LUMO转移到Pc的LUMO的过程产生。
A novel method for the fabrication of a charge‐transfer complex crystal was developed. Photoirradiation of a solution of TPP[Co(tbp)(CN)2] and TPP[Co(Pc)(CN)2] (tbp=tetrabenzoporphyrin, Pc=phthalocyanine, TPP=tetraphenylphosphonium) gave a molecular conducting crystal of a charge‐transfer complex TPP[Co(tbp)(CN)2]2, which was produced by the process in which the photoexcited electron in tbp was transferred from the LUMO of tbp to that of Pc.