An N-Heterocyclic Carbene as a Nucleophilic Catalyst for Cyanosilylation of Aldehydes
An N-Heterocyclic Carbene as a Nucleophilic Catalyst for Cyanosilylation of Aldehydes
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DOI：
10.1055/s-2005-918520
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发表时间：
2006-02
期刊：
影响因子：
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通讯作者：
Y. Fukuda;Y. Maeda;Satoru Ishii;K. Kondo;T. Aoyama
中科院分区：
文献类型：
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作者：
Y. Fukuda;Y. Maeda;Satoru Ishii;K. Kondo;T. Aoyama
本文报道了在1，3-二（2，4，6-三甲基苯基）咪唑鎓氯化物和叔丁醇钾制得的N-杂环卡宾作为亲核催化剂存在下，醛与三甲基硅腈的硅腈化反应的第一种方法。
The first method for cyanosilylation of aldehydes with trimethylsilyl cyanide in the presence of the N-heterocyclic carbene prepared from 1,3-bis(2,4,6-trimethylphenyl)imidazolium chloride and potassium tert-butoxide, as a nucleophilic catalyst, is described.