Syntheses and structures of copper benzene-1,4-dioxydiacetate complexes with 4,4′-bipyridine and 1,10-phenanthroline
Syntheses and structures of copper benzene-1,4-dioxydiacetate complexes with 4,4′-bipyridine and 1,10-phenanthroline
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DOI：
10.1080/00958972.2010.495776
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发表时间：
2010-06
影响因子：
1.9
通讯作者：
Yun-Nan Gong;Chong-Bo Liu;Yuan Ding;Zhi-Qiang Xiong;Lian-Ming Xiong
中科院分区：
文献类型：
--
作者：
Yun-Nan Gong;Chong-Bo Liu;Yuan Ding;Zhi-Qiang Xiong;Lian-Ming Xiong
Two new copper complexes, [Cu2(BDOA)(4,4′-bpy)2] ⋅ 2H2O (1) and [Cu(BDOA)(phen)] (2) (H2BDOA = benzene-1,4-dioxydiacetic acid; 4,4′-bpy = 4,4′-bipyridine; phen = 1,10-phenanthroline), were synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction. Complex 1 exhibits a 2-D three-connected network structure with 63 topology. Complex 2 displays a 1-D chain structure. Furthermore, the 3-D supramolecular networks of 1 and 2 are constructed via rich hydrogen bonds. Thermal stability of 1 is discussed in this article.
