40Ar/39Ar Single Grain Dating and Mineral Chemistry of Hornblendes South of the Red River Shear Zone (Vietnam): New Evidence for Early Proterozoic Tectonothermal Event
40Ar/39Ar Single Grain Dating and Mineral Chemistry of Hornblendes South of the Red River Shear Zone (Vietnam): New Evidence for Early Proterozoic Tectonothermal Event
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DOI:
10.1016/s1342-937x(05)70914-x
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发表时间:
2002-10
影响因子:
6.1
通讯作者:
T. N. Nam;H. Hyodo;T. Itaya;T. Matsuda
中科院分区:
文献类型:
--
作者:
T. N. Nam;H. Hyodo;T. Itaya;T. Matsuda
The pre-Mesozoic metamorphic belt runs parallel to the Day Nui Con Voi - Red River shear zone in Vietnam to the south. The belt is mainly composed of hornblende gneisses, amphibolite lenses and mica-schists. Five hornblendes from a gneiss and an amphibolite were analyzed chemically and chronologically by Electron Probe Micro Analysis (EPMA) and40Ar/39Ar methods. EPMA analyses show that hornblendes in the gneiss and the amphibolite have significant amount of edenite component and similar average composition. However, the recalculated Fe3+content is significantly heterogeneous in a thin section while total Fe is nearly the same among the analyses. The rim of each crystal is higher in Fe3+/(Fe3++ Fe2+) than the core. These chemical and petrological features suggest that the hornblendes have suffered significant oxidation, in particular, largely in the gneiss.40Ar/39Ar analyses showed that the gneiss has a significant variation of plateau ages (2089±14, 1977±19 and 1873±13 Ma) among three hornblende grains, whereas the amphibolite gives the same plateau ages (2056±14 and 2044±21 Ma) for two grains. All grains of both samples have excess ages in the first few fractions at low temperatures and partial-loss ages between the excess and plateau spectra. The Ca/K ratios indicate some disturbed phases for the lower temperature spectra but the partial-loss ages are also derived from hornblende phase. These facts suggest that hornblende in the gneiss has experienced partial argon loss by oxidation and/or thermally activated argon diffusion process. However, the gneiss and the associated amphibolite have preserved the early Proterozoic tectono-metamorphic event in the hornblende crystals except for their rims, giving new evidence for the early Proterozoic event within the pre-Mesozoic metamorphic belt (northern Vietnam) south of the Red River shear zone in Indochina.