Theoretical analysis of the time-resolved binary (e, 2e) binding energy spectra on three-body photodissociation of acetone at 195 nm
Theoretical analysis of the time-resolved binary (e, 2e) binding energy spectra on three-body photodissociation of acetone at 195 nm
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195 nm 丙酮三体光解时间分辨二元 (e, 2e) 结合能谱的理论分析
DOI：
10.1088/1742-6596/875/2/012004
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发表时间：
2017
期刊：
影响因子：
--
通讯作者：
Takahashi M
中科院分区：
文献类型：
--
作者：
Yamazaki M;Nakayama S;Zhu C Y;Takahashi M
报道了氢化丙酮分子195 nm光解动力学的时间分辨(e，2e)电子动量谱的理论进展。我们检验了预测的最小能量反应路径，以考察相关的(e，2e)计算是否符合实验结果。在约10 eV的结合能附近发现了实验和计算之间的显著差异，这表明观察到的差异可能至少部分起源于从未考虑过的非最小能量路径。
We report on theoretical progress in time-resolved (e, 2e) electron momentum spectroscopy of photodissociation dynamics of the deuterated acetone molecule at 195 nm. We have examined the predicted minimum energy reaction path to investigate whether associated (e, 2e) calculations meet the experimental results. A noticeable difference between the experiment and calculations has been found at around binding energy of 10 eV, suggesting that the observed difference may originate, at least partly, in ever-unconsidered non-minimum energy paths.