Chemical Structure and Performance of a Novel Polyimide-urethane Composite Reverse Osmosis Membrane Material

Chemical Structure and Performance of a Novel Polyimide-urethane Composite Reverse Osmosis Membrane Material
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发表时间:
2012
影响因子:
1
通讯作者:
Liu Li
Liu Li
中科院分区:
化学4区
文献类型:
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作者:
Liu Li

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常见的芳香族聚酰胺复合反渗透(RO)膜易氧化,以N,N'-二甲基间苯二胺(DMMPD)为关键功能单体,与5-氯甲酰氧基间苯二甲酰氯(CFIC)反应,采用界面聚合技术制备了耐氯聚酰亚胺-聚氨酯RO膜材料。 X射线光电子能谱(XPS),测定了膜的耐氯性能,并分析了膜活性层的化学结构与耐氯性能的关系。
The common aromatic polyamide composite reverse osmosis(RO) membrane is easy to be oxidated.Chlorine resistance polyimide-urethane RO membrane material by interfacial polymerization technology was prepared with N,N′-dimethyl-m-phenylenediamine(DMMPD) as a key functional monomer which reacted with 5-choroformyloxyisophthaloyl chloride(CFIC).The surface chemical structures of membrane active layer were analyzed by combination of attenuated total reflectance infrared(ATR-IR) and X-ray photoelectronic spectroscopy(XPS),and the chlorine resistance performance of membrane was also measured.Furthermore,the relationship between chemical structure of membrane active layer and chlorine-resistant performance was analyzed.