Facile assembly of partly graphene-enveloped sulfur composites in double-solvent for lithium–sulfur batteries
Facile assembly of partly graphene-enveloped sulfur composites in double-solvent for lithium–sulfur batteries
复制标题
在双溶剂中轻松组装部分石墨烯包封的硫复合材料，用于锂硫电池
DOI：
10.1016/j.electacta.2015.07.174
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发表时间：
2015-10
影响因子：
6.6
通讯作者：
Shao, Guosheng
中科院分区：
文献类型：
--
作者：
Chen, Weihua;Hu, Junhua;Mao, Jing;Shao, Guosheng
A series of graphene-enveloped sulfur (G/S) composites with different sulfur particle sizes and high sulfur contents of 82 wt% are synthesized using a double solvent approach for lithium–sulfur batteries. This double solvent approach is facile, low cost, and effective in preparing graphene–sulfur composites for large-scale production. Scanning electron microscopy and energy dispersive X-ray spectroscopy mapping were used to verify the structure and composition of the G/S composites. The graphene-coating layers not only provide a conductive carbon matrix surrounding the sulfur particles but also prevent the soluble polysulfide intermediates dissolving into the electrolyte. The sizes of sulfur particles can be controlled by adjusting the ratios of double solvent (CS2/alcohol) and may further affect the electrochemical behavior. When used as cathode materials for lithium–sulfur batteries, the G/S-200 composite with the smallest sulfur particle size shows an initial discharge capacity of 1068.5 mAh g−1and retains 729.5 mAh g−1after 100 cycles at 0.1C. This novel double solvent method is a promising approach to obtain other carbon sulfur composites.
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