Expanding Boundaries: N2 Cleavage and Functionalization beyond Early Transition Metals
Expanding Boundaries: N2 Cleavage and Functionalization beyond Early Transition Metals
复制标题
DOI：
10.1002/anie.201603142
复制
发表时间：
2016-07-04
影响因子：
16.6
通讯作者：
Chirik, Paul J.
中科院分区：
文献类型：
--
作者：
Bezdek, Mate J.;Chirik, Paul J.
众所周知，早期过渡金属可以催化 N2 的裂解和官能化。在本摘要中，总结了最近的工作，表明铼催化剂也能够完成这项艰巨的任务，并提出了将大气中的 N2 化学计量掺入乙腈的合成循环。
Early transition metals are well known to catalyze the cleavage and functionalization of N2. In this Highlight, recent work showing that a rhenium catalyst is also capable of carrying out this difficult task is summarized, and a synthetic cycle for the stoichiometric incorporation of atmospheric N2 into acetonitrile is presented.