Ruthenium(II) complexes with 8-(diphenylphosphino)quinoline: Synthesis, spectroscopic properties, and single-crystal X-ray structures
Ruthenium(II) complexes with 8-(diphenylphosphino)quinoline: Synthesis, spectroscopic properties, and single-crystal X-ray structures
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钌 (II) 与 8-(二苯基膦)喹啉的配合物：合成、光谱性质和单晶 X 射线结构
DOI：
10.1080/15533174.2016.1212225
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发表时间：
2017
期刊：
影响因子：
--
通讯作者：
H. Hodali
中科院分区：
文献类型：
--
作者：
M. A. Al;F. Awwadi;Rasha K. Al;H. Hodali
摘要本文报道了两种新的8-二苯基膦喹啉(N-P)与Ru(II)的配合物的合成和表征。用FT-IR、UV-Vis、X-射线单晶等方法对配合物[Ru(N-P)(DMSO)2Cl2](1)和[Ru(N-P)2Cl2](2)进行了表征。测定了分别在三斜空间群P-1和正交空间群Pbca中结晶的(1)和(2)的单晶X射线结构。X-射线结构分析表明，Ru中心周围的几何构型为扭曲的八面体。键长分析表明，反式影响的顺序为：P>；N>；S>；
ABSTRACT This work describes the synthesis and characterization of two new ruthenium(II) complexes with 8-diphenylphosphinoquinoline (N-P). The complexes [Ru(N-P)(DMSO)2Cl2] (1), where DMSO = dimethyl sulfoxide, and [Ru(N-P)2Cl2] (2) were characterized by FT-IR, UV-Vis spectrometer, and X-ray crystallography. Single-crystal X-ray structures of (1) and (2), which crystallize in the triclinic space group P-1 and orthorhombic space group Pbca, respectively, have been determined. The X-ray structural analyses of both complexes indicate that the geometries around the Ru center are distorted octahedral. Bond length analysis indicates a trans influence in the order: P > N > S > Cl.