Synthesis of the female sex pheromone of the citrus mealybug, Planococcus citri
Synthesis of the female sex pheromone of the citrus mealybug, Planococcus citri
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DOI：
10.1021/jf035301h
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发表时间：
2004-05-19
影响因子：
6.1
通讯作者：
Webster, FX
中科院分区：
文献类型：
--
作者：
Passaro, LC;Webster, FX
柑橘粉蚧是美国南部的一种常见害虫。S.和地中海。本文报道了雌虫性信息素（1 R）-（+）-cis-2，2-二甲基-3-异丙烯基环丁烷甲醇乙酸酯的两种合成方法。关键的转化包括（1 R）-（+）-α-蒎烯丙基氧化为（+）-R-马鞭草烯酮，使用RuCl 3-NalO（4）进行氧化脱羧，以及使用Zn/CH 2Br 2/TiCl 4进行亚甲基化。
The citrus mealybug, Planococcus citri (Risso) is a common pest in the Southern U. S. and the Mediterranean. Two alternative syntheses of the female sex pheromone, (1R)-(+)-cis-2,2-dimethyl-3-isopropenyl-cyclobutane methanol acetate, have been developed. Key transformations include an allylic oxidation of (1R)-(+)-alpha-pinene to (+)-R-verbenone, oxidative decarboxylation using RuCl3-NalO(4), and methylenation with Zn/CH2Br2/TiCl4.