Palladium‐Catalyzed C‐H Bond Ortho Acylation/Annulation with Toluene Derivatives

Palladium‐Catalyzed C‐H Bond Ortho Acylation/Annulation with Toluene Derivatives
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DOI：
10.1002/ajoc.201500417
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发表时间：
2016
期刊：
Asian Journal of Organic Chemistry
影响因子：
2.7
通讯作者：
Lingyun Yang;Li Han;Bin Xu;Leilei Zhao;Jinpei Zhou;Huibin Zhang
Lingyun Yang;Li Han;Bin Xu;Leilei Zhao;Jinpei Zhou;Huibin Zhang
中科院分区：
化学3区
文献类型：
--
作者：
Lingyun Yang;Li Han;Bin Xu;Leilei Zhao;Jinpei Zhou;Huibin Zhang

文献摘要

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介绍了钯催化苯酰胺和甲苯级联交叉偶联合成3-羟基异吲哚酮的方法。该方法允许用Pd/ thbhp系统以原子经济和环境友好的方式进行C−H键邻位酰化/环化。此外，多种底物都有良好的耐受性。
A palladium-catalyzed cascade cross-coupling of benzamide and toluene for the synthesis of 3-hydroxyisoindolin-1-one is described. This method allows C−H bond ortho acylation/annulation with a Pd/TBHP system in an atom-economical and environmentally friendly manner. In addition, a variety of substrates are well tolerated.