Raman Study of Glasses of Ba2TiSi2O8 and Ba2TiGe2O8

Raman Study of Glasses of Ba2TiSi2O8 and Ba2TiGe2O8
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Ba2TiSi2O8和Ba2TiGe2O8玻璃的拉曼研究

DOI:
10.1111/j.1151-2916.1992.tb05629.x
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发表时间:
1992
影响因子:
3.9
通讯作者:
A. Bhalla
A. Bhalla
中科院分区:
材料科学2区
文献类型:
--
作者:
S. A. Markgraf;Shiv k. Sharma;A. Bhalla

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报道了钡钛锗(Ba 2 Ti(Si,Ge)2 O 8)玻璃的拉曼光谱,并对Ba 2 TiSi 2 O 8和Ba 2 TiGe 2 O 8的相应晶体粉末和玻璃的拉曼光谱进行了比较. Ba 2 TiGe 2 O 8玻璃的光谱与Ba 2 TiGe 2 O 8晶体的拉曼光谱相一致,玻璃中的Raman(Ge-O-Gea)模位于518 cm-1,晶体中的Raman(Ge-O-Gea)模位于521 cm-1
Raman spectra are reported for fresnoite (Ba 2 Ti(Si, Ge) 2 O 8 glasses, and comparison is made between the Raman spectra of the corresponding crystalline powders and glassess of Ba 2 TiSi 2 O 8 and Ba 2 TiGe 2 O 8 . The Ba 2 TiGe 2 O 8 glass spectra show correspondence with the Ba 2 TiGe 2 O 8 crystalline Raman spectra; the υ s (Ge-O-Gea mode occurs at 518 cm -1 in the glass and at 521 cm -1 in the crystalline material