Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters
Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters
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DOI：
10.1039/c3cc40352a
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发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Kim, Eunsuk
中科院分区：
文献类型：
--
作者：
Fitzpatrick, Jessica;Kalyvas, Harris;Kim, Eunsuk
报道了一系列带有硫醇盐配体的{Fe(NO)(2)}(9)二亚硝基铁络合物与分子氧的反应性。这些反应导致相应的鲁辛红酯的形成以及硫醇盐的氧化。这种反应性与之前报道的 {Fe(NO)(2)}(10) 配合物的反应性形成对比。
The reactivity of a series of {Fe(NO)(2)}(9) dinitrosyl iron complexes bearing thiolate ligands with molecular oxygen is reported. These reactions result in the formation of the corresponding Roussin's red esters along with thiolate oxidation. This reactivity is contrasted with that previously reported for {Fe(NO)(2)}(10) complexes.