SINGLE ELECTRON-TRANSFER IN THE ADDITION OF CHIRAL DIPOLE-STABILIZED ORGANOLITHIUMS TO CARBONYLS - STEREOCHEMISTRY OF A CHIRAL NUCLEOPHILE AS A MECHANISTIC PROBE
SINGLE ELECTRON-TRANSFER IN THE ADDITION OF CHIRAL DIPOLE-STABILIZED ORGANOLITHIUMS TO CARBONYLS - STEREOCHEMISTRY OF A CHIRAL NUCLEOPHILE AS A MECHANISTIC PROBE
复制标题
DOI：
10.1016/0040-4039(91)85007-r
复制
发表时间：
1991-04-22
影响因子：
1.8
通讯作者：
GAWLEY, RE
中科院分区：
文献类型：
--
作者：
REIN, KS;CHEN, ZH;GAWLEY, RE
光谱和立体化学证据表明，单电子转移(SET)可以解释金属化联戊酰胺和恶唑啉与羰基反应中观察到的选择性差异。
Spectroscopic and stereochemical evidence is provided which suggests that single electron transfer (SET) accounts for the difference in selectivity observed in the reaction of metalated pivalamides and oxazolines with carbonyls.