A high-performance oxygen evolution electrode of nanoporous Ni-based solid solution by simulating natural meteorites
A high-performance oxygen evolution electrode of nanoporous Ni-based solid solution by simulating natural meteorites
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模拟天然陨石制备纳米多孔镍基固溶体高性能析氧电极
DOI：
10.1016/j.cej.2020.128340
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发表时间：
2021-04
影响因子：
15.1
通讯作者：
Zhong Jin
中科院分区：
文献类型：
--
作者：
Boya Hao;Zhiguo Ye;Jilin Xu;Liangliang Li;Juntong Huang;Xinyuan Peng;Duosheng Li;Zhong Jin
Transforming the intermittent solar and wind energies into green hydrogen energy by water electrolysis is deemed to be a promising approach to substitute traditional fossil energies. However, the scarcity of precious IrO2/RuO2-based metal oxides for oxygen evolution reaction hinders the large-scale utilization. Here, based on the nanoscale Kirkendall effect, we fabricate nanoporous γ-Ni based solid solution with the simulated FeCoNi surface compositions of Gibeon meteorites by a facile microwave sintering method. A metal (oxy)hydroxide layer with a thickness of approximately 9 nm was formed on the surface of as-prepared electrode after aging, achieving an overpotential of only 254 mV at 10 mA cm−2and a low Tafel slope of 37.0 mV dec−1. The electrode exhibits outstanding long-term stability in a wide range of current densities without compromising the electrocatalytic activity, which is attributed to the 3D-interconnected nanoporous structure, synergistic effect of different species, high conductivity and excellent wettability. The fabrication of nanoporous non-precious solid solution architectures which mimic naturally-formed materials provides a feasible strategy for the design of high-performance electrocatalysts towards clean energy applications.
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影响因子：
16.6
作者：
Lu, Xunyu;Zhao, Chuan
通讯作者：
Zhao, Chuan
影响因子：
22.1
作者：
Li, Chaojiang;Zhang, Bowei;Huang, Yizhong
通讯作者：
Huang, Yizhong
锚定在非晶镍钴硫化物片上的 NiCo-DH 纳米点作为析氧反应的有效电催化剂
影响因子：
6.6
作者：
Zhao Huihui;Yang Yang;Dai Xiaoping;Qiao Hongyan;Yong Jiaxi;Luan Xuebin;Yu Lei;Luan Chenglong;Wang Yao;Zhang Xin
通讯作者：
Zhang Xin
DOI：
--
发表时间：
1995-02
期刊：
--
影响因子：
--
作者：
J. Moulder;J. Chastain;R. C. King
通讯作者：
J. Moulder;J. Chastain;R. C. King
影响因子：
3.9
作者：
Y. Bykov;S. V. Egorov;A. Eremeev;V. Kholoptsev;I. Plotnikov;K. Rybakov;A. A. Sorokin-A.;S. Balabanov-S.-Balab
通讯作者：
Y. Bykov;S. V. Egorov;A. Eremeev;V. Kholoptsev;I. Plotnikov;K. Rybakov;A. A. Sorokin-A.;S. Balabanov-S.-Balab