Sandwich-like octacyanometalate-based cadmium assemblies with the 4,4′-dipyridyl sulfide ligand
Sandwich-like octacyanometalate-based cadmium assemblies with the 4,4′-dipyridyl sulfide ligand
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DOI：
10.1039/c4ce00965g
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发表时间：
2014-08
期刊：
影响因子：
3.1
通讯作者：
Dan Yang;Hu Zhou;Aihua Yuan;Yi-zhi Li
中科院分区：
文献类型：
--
作者：
Dan Yang;Hu Zhou;Aihua Yuan;Yi-zhi Li
通过八氰钨酸盐、镉离子和4，4 ′-联吡啶硫醚配体的自组装反应，首次合成出了基于八氰钨酸盐的镉化合物，它们具有新颖的类镉配位网络。讨论了溶剂和温度对产物形成的影响。
The self-assembly of octacyanotungstate, cadmium ions, and 4,4′-dipyridyl sulfide ligands has isolated the first octacyanometalate-based cadmium compounds, which exhibit novel sandwich-like coordination networks. The effect of solvent and temperature on the formation of products was discussed.