Arene-ligated heteroleptic terphenolate complexes of thorium.
Arene-ligated heteroleptic terphenolate complexes of thorium.
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DOI:
10.1039/c4dt02995j
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发表时间:
2014-11
影响因子:
4
通讯作者:
Jamie McKinven;G. Nichol;P. Arnold
中科院分区:
文献类型:
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作者:
Jamie McKinven;G. Nichol;P. Arnold
Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th-η(6)-arene interactions in a thorium bis(arene) sandwich motif.