Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT).
Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT).
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作者：
新的支化聚合提供了以前无法获得的大分子，对结构的理解非常重要，因为它提供了对支化机制的洞察并能够确定结构-性能关系。在这里，我们提出了来自最近报道的转移主导支化自由基调聚 (TBRT) 方法的材料的详细反门控 13C NMR 表征，以量化支化并提供对环化的深入了解。支化的表征和定量是理解新的复杂大分子的关键。在这里，我们建立了方法来评估由转移主导的分支自由基端粒化（TBRT）形成的独特和新颖的结构。
New branched polymerisations offer previously inaccessible macromolecules and architectural understanding is important as it provides insight into the branching mechanism and enables the determination of structure–property relationships. Here we present a detailed inverse gated 13C NMR characterisation of materials derived from the very recently reported Transfer-dominated Branching Radical Telomerisation (TBRT) approach to quantify branching and provide an insight into cyclisation. The characterisation and quantification of branching is key to understanding new complex macromolecules. Here we establish approaches to evaluate the unique and novel architectures formed by Transfer-dominated Branching Radical Telomerisation (TBRT).
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影响因子：
4.3
作者：
Gaborieau, Marianne;Castignolles, Patrice
通讯作者：
Castignolles, Patrice
影响因子：
56.9
作者：
FRECHET, JMJ;HENMI, M;GRUBBS, RB
通讯作者：
GRUBBS, RB
影响因子：
3.4
作者：
Bannister, Iveta;Billingham, Norman C.;Armes, Steven P.
通讯作者：
Armes, Steven P.
影响因子：
1.4
作者：
Gaborieau, Marianne;Gilbert, Robert G.;Castignolles, Patrice
通讯作者：
Castignolles, Patrice
影响因子：
3.4
作者：
Alhilfi, Tamara;Chambon, Pierre;Rannard, Steve P.
通讯作者：
Rannard, Steve P.