Electrochemistry and Langmuir Trough Studies of C60 and C70 Films
Electrochemistry and Langmuir Trough Studies of C60 and C70 Films
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DOI：
10.1021/ja00037a030
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发表时间：
1992-05
影响因子：
15
通讯作者：
C. Jehoulet;Y. Obeng;Yeon Kim;F. Zhou;A. Bard
中科院分区：
文献类型：
--
作者：
C. Jehoulet;Y. Obeng;Yeon Kim;F. Zhou;A. Bard
Thin films of the fullerenes C 60 and C 70 , formed by solution casting, were studied by cyclic voltammetry (CV) in MeCN solutions containing quaternary ammonium or alkali-metal salts as supporting electrolytes. The film shows four CV reduction waves and one oxidation wave. The CV behavior for the first reduction, coulometrically equivalent to a one-electron reduction, indicates a large structural reorganization of the film with intercalation of the supporting electrolyte cation and a small amount of dissolution. Upon oxidation of the reduced form, the structure rearranges to form the parent
