REACTION MECHANISMS FOR ELECTROCHEMICAL CARBON-SKELETON REARRANGEMENT AS CATALYZED BY HYDROPHOBIC VITAMIN B12 IN NONAQUEOUS MEDIA
REACTION MECHANISMS FOR ELECTROCHEMICAL CARBON-SKELETON REARRANGEMENT AS CATALYZED BY HYDROPHOBIC VITAMIN B12 IN NONAQUEOUS MEDIA
复制标题
非水介质中疏水性维生素 B12 催化电化学碳骨架重排的反应机制
DOI：
10.1246/cl.1986.555
复制
发表时间：
1986
影响因子：
1.6
通讯作者：
Y. Matsuda
中科院分区：
文献类型：
--
作者：
Y. Murakami;Y. Hisaeda;Takako Tashiro;Y. Matsuda
阐明了疏水维生素B12催化2，2-二(乙氧羰基)-1-溴丙烷在−1.0V、−1.5V和−2.0V下控制电位电解的反应机理。碳骨架重排被认为是通过形成阴离子中间体进行的。
Reaction mechanisms for the controlled-potential electrolysis of 2,2-bis(ethoxycarbonyl)-1-bromopropane at −1.0, −1.5, and −2.0 V vs. SCE as catalyzed by a hydrophobic vitamin B12 were clarified. The carbon-skeleton rearrangement was postulated to proceed via formation of anionic intermediates.