Simultaneous and Direct Fabrication of Lithium Cobalt Oxide Film and Powder Using Soft Solution Processing at 100 ° C
Simultaneous and Direct Fabrication of Lithium Cobalt Oxide Film and Powder Using Soft Solution Processing at 100 ° C
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采用 100 °C 软溶液加工同时直接制备锂钴氧化物薄膜和粉末
DOI：
10.1149/1.1390735
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发表时间：
1999
影响因子：
--
通讯作者：
M. Yoshimura
中科院分区：
文献类型：
--
作者：
Kyooseung Han;Seung‐Wan Song;Tomoaki Watanabe;M. Yoshimura
在100 ℃下，在3 M LiOH溶液中使用软溶液处理，在单一合成步骤中同时制备作为锂可再充电电池阴极的锂钴氧化物膜和粉末，而不进行任何合成后退火。通过X射线衍射图谱分析、拉曼光谱、X射线光电子能谱、Co K边X射线吸收近边结构谱和循环伏安法对它们的结构、化学组成和电化学活性进行了检测。虽然在Co金属基底的水热处理时以沉淀物形式制备块状形式的层状LiCoO 2，但是在Co金属基底的表面上获得混合层状和尖晶石锂钴氧化物膜。S1099-0062（98）04-025-5。All rights reserved.
Lithium cobalt oxide film and powder as cathodes for lithium rechargeable batteries were simultaneously prepared in a single synthetic step using soft solution processing in 3 M LiOH solution at 100 C without any postsynthesis annealing. Their structure, chemical composition, and electrochemical activity were checked by X-ray diffraction pattern analysis, Raman spectroscopy, X-ray photoelectron spectroscopy, Co K-edge X-ray absorption near edge structure spectroscopy, and cyclic voltammetry. While layered LiCoO2 in bulk form was prepared as a precipitate upon the hydrothermal treatment of Co metal substrates, mixed layered and spinel lithium cobalt oxide film was obtained on the surface of the Co metal substrate.© 1999 The Electrochemical Society. S1099-0062 (98) 04-025-5. All rights reserved.