Highly enantioselective asymmetric autocatalysis using chiral ruthenium complex-ion-exchanged synthetic hectorite as a chiral initiator.
Highly enantioselective asymmetric autocatalysis using chiral ruthenium complex-ion-exchanged synthetic hectorite as a chiral initiator.
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DOI：
10.1039/b823282b
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发表时间：
2009-03
影响因子：
3.2
通讯作者：
Tsuneomi Kawasaki;T. Omine;Kenta Suzuki;Hisako Sato;A. Yamagishi;K. Soai
中科院分区：
文献类型：
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作者：
Tsuneomi Kawasaki;T. Omine;Kenta Suzuki;Hisako Sato;A. Yamagishi;K. Soai
The synthetic hectorite containing intercalated chiral Delta- and Lambda-tris(1,10-phenanthroline)ruthenium(II) ions acts as a heterogeneous chiral catalyst in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde to afford, in combination with asymmetric autocatalytic amplification of enantiomeric excess, 5-pyrimidyl alkanol with high enantiomeric excess.
