Liquid chromatography–mass spectrometry analysis of cationic aniline dyes from the Technical University of Dresden Historical Collection of Dyes
Liquid chromatography–mass spectrometry analysis of cationic aniline dyes from the Technical University of Dresden Historical Collection of Dyes
复制标题
对德累斯顿工业大学染料历史收藏中的阳离子苯胺染料进行液相色谱-质谱分析
DOI：
10.1177/1747519819901103
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发表时间：
2020
影响因子：
1.4
通讯作者：
H. Hartmann
中科院分区：
文献类型：
--
作者：
M. Plater;A. Raab;H. Hartmann
液相色谱-质谱法已用于分析 19 世纪的一系列阳离子苯胺染料。钱德勒博物馆的紫红色被用作比较的标准。它由典型的 W. H. Perkin 紫红色 A 和 B 混合物组成。来自德累斯顿历史收藏品的紫红色则不同，主要由紫红色 A 和单甲基紫红色发色团组成。讨论了可能的合成路线及其意义。已分析了三个苯代玫瑰苯胺样品，并编制了 19 种可能成分的清单。液相色谱-质谱分析对这种复杂的混合物效果很好，可以提供有关保留时间和准确质量分子量的清晰信息。两个样品中存在单苯基玫瑰苯胺、二苯基玫瑰苯胺和三苯基玫瑰苯胺，第三个样品主要含有单苯基玫瑰苯胺。在每个样品中，出现少量较高分子量的同系物。薄层色谱板从左到右依次为品红或玫瑰苯胺，然后是单、二和三苯基玫瑰苯胺。右侧的两个点是蓝色的，左侧的两个点是红色的。
Liquid chromatography–mass spectrometry has been used to analyse a range of cationic aniline dyes from the 19th century. Mauveine from the Chandler museum is used as a standard for comparison. This consists of a typical W. H. Perkin mixture of mauveine A and B. Mauveine from a historic collection in Dresden is different and consists of mainly mauveine A and a monomethyl mauveine chromophore. Possible synthetic routes and its significance are discussed. Three samples of phenylated rosanilines have been analysed, and a list of 19 possible components compiled. An analysis by liquid chromatography–mass spectrometry works well on this complex mixture giving clear information on retention times and accurate mass molecular weights. Mono-, di- and triphenylrosanilines are present in two samples, and a third sample has mainly monophenylrosaniline. In each sample, a small amount of higher molecular weight homologues appear. The thin-layer chromatography plate, from left to right, has fuchsin or rosaniline then mono-, di- and triphenylrosaniline. The two spots on the right-hand side are blue, and the two spots on the left-hand side are red.