A neutral Pt3 stack unsupported by any bridging ligand.
A neutral Pt3 stack unsupported by any bridging ligand.
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DOI:
10.1039/c0dt01408g
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发表时间:
2011-04
影响因子:
4
通讯作者:
Lars Holland;Wei-zheng Shen;Philipp von Grebe;Pablo J. Sanz Miguel;F. Pichierri;A. Springer;C. Schalley;B. Lippert
中科院分区:
文献类型:
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作者:
Lars Holland;Wei-zheng Shen;Philipp von Grebe;Pablo J. Sanz Miguel;F. Pichierri;A. Springer;C. Schalley;B. Lippert
Pt···Pt···Pt interactions via their d(8) orbitals, combined with π-π stacking of deprotonated, chelating 2-(3'-pyrazolyl)pyridine (pyzpy) ligands, are responsible for trans-Pt(pyzpy)(2) (2) crystallization in a stack of three molecules unsupported by any bridging ligand.