A neutral Pt3 stack unsupported by any bridging ligand.

A neutral Pt3 stack unsupported by any bridging ligand.
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DOI:
10.1039/c0dt01408g
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发表时间:
2011-04
影响因子:
4
通讯作者:
Lars Holland;Wei-zheng Shen;Philipp von Grebe;Pablo J. Sanz Miguel;F. Pichierri;A. Springer;C. Schalley;B. Lippert
Lars Holland;Wei-zheng Shen;Philipp von Grebe;Pablo J. Sanz Miguel;F. Pichierri;A. Springer;C. Schalley;B. Lippert
中科院分区:
化学2区
文献类型:
--
作者:
Lars Holland;Wei-zheng Shen;Philipp von Grebe;Pablo J. Sanz Miguel;F. Pichierri;A. Springer;C. Schalley;B. Lippert

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铂通过d(8)轨道相互作用,结合去质子化的2-(3‘-吡唑基)吡啶(3’-吡唑基)吡啶(Py)配体的π-π堆积,导致了三个分子堆叠中的反式铂(Py)(2)(2)结晶,没有任何桥联配体支撑。
Pt···Pt···Pt interactions via their d(8) orbitals, combined with π-π stacking of deprotonated, chelating 2-(3'-pyrazolyl)pyridine (pyzpy) ligands, are responsible for trans-Pt(pyzpy)(2) (2) crystallization in a stack of three molecules unsupported by any bridging ligand.