ACID CATALYSIS AND THE MECHANISM OF DECOMPOSITION OF BIS-PHENYLACETYL PEROXIDE
ACID CATALYSIS AND THE MECHANISM OF DECOMPOSITION OF BIS-PHENYLACETYL PEROXIDE
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DOI：
10.1021/ja01163a064
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发表时间：
1950-01-01
影响因子：
15
通讯作者：
LEFFLER, JE
中科院分区：
文献类型：
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作者：
BARTLETT, PD;LEFFLER, JE
过氧化双苯乙酰（I）在0时的分解速度略快于过氧化苯甲酰在70时的分解速度。我们最初研究它是希望它可能被证明是一个有用的引发剂的低温聚合，并了解其严重的不稳定性的原因。分解产物。过氧化二苯乙酰在甲苯、四氯化碳和邻氯甲苯中分解。基-
Bis-phenylacetyl peroxide(I) decomposes slightly faster at 0 than benzoyl peroxide does at 70. We investigated it originally in the hope that it might prove a useful initiator for lowtemperature polymerization, and to learn the reason for its great instability. Products of Decomposition.—Bis-phenylacetyl peroxide was decomposed in toluene, in carbon tetrachloride and in o-chlorotoluene. The ki-