Spectral differentiation and gas chromatographic/mass spectrometric analysis of the lacrimators 2-chloroacetophenone and o-chlorobenzylidene malononitrile.

Spectral differentiation and gas chromatographic/mass spectrometric analysis of the lacrimators 2-chloroacetophenone and o-chlorobenzylidene malononitrile.
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DOI:
10.1520/jfs12298j
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发表时间:
1986-04
影响因子:
1.6
通讯作者:
K. Ferslew;R. H. Orcutt;A. N. Hagardorn
K. Ferslew;R. H. Orcutt;A. N. Hagardorn
中科院分区:
医学4区
文献类型:
--
作者:
K. Ferslew;R. H. Orcutt;A. N. Hagardorn

文献摘要

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2-氯苯乙酮(CN)和邻氯苄叉丙二腈(CS)是美国最常用的催泪剂。文献中缺乏关于这些化合物的完整光谱数据。光谱数据(紫外线、荧光、质子核磁共振和红外线)和气液色谱/质谱法,区分和识别氯化萘和氯化萘。这些方法和数据被用来识别法医学标本从意外中毒。
2-Chloroacetophenone (CN) and o-chlorobenzylidene malononitrile (CS) are the most common chemical agents used as lacrimators in the United States. There is a lack of complete spectral data on these compounds in the literature. Spectral data (ultraviolet, fluorescence, proton nuclear magnetic resonance, and infrared) and a gas-liquid chromatographic/mass spectrometric method are presented that differentiate and identify CN and CS. These methods and data were used to identify a forensic science specimen from an accidental intoxication.