A CRITICAL REVIEW OF EQUILIBRIUM DATA FOR PROTON- AND METAL COMPLEXES OF 1,10-PHENANTHROLINE, 2,2′-BIPYRIDYL AND RELATED COMPOUNDS
A CRITICAL REVIEW OF EQUILIBRIUM DATA FOR PROTON- AND METAL COMPLEXES OF 1,10-PHENANTHROLINE, 2,2′-BIPYRIDYL AND RELATED COMPOUNDS
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1,10-菲咯啉、2,2-联吡啶及相关化合物的质子和金属配合物平衡数据的严格审查
DOI：
10.1016/b978-0-08-022344-5.50004-8
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发表时间：
1978
期刊：
影响因子：
--
通讯作者：
W. Mcbryde
中科院分区：
文献类型：
--
作者：
W. Mcbryde
《1，10-菲咯啉、2，2 '-联吡啶及其相关化合物的质子和金属络合物平衡数据的评论》是1，10-菲咯啉鎓和2，2'-联吡啶鎓离子及其衍生物的酸度常数的汇编，以及由这些共轭碱形成的金属络合物的稳定常数。这些平衡数据进行了严格审查。本专论包括在非水或混合溶剂中测定的值，以及大量含有这些碱和第二配体的”混合”金属络合物的值。该调查还包含了质子和金属离子络合物的形成熵和熵的已知值。该汇编指出了平衡常数适用的条件以及确定这些常数的方法。化合物的酸碱性质由菲咯啉鎓或联吡啶鎓离子的酸度常数表示，表示为pK值。几乎所有列出的值都是通过电位法或电化学法获得的，这两种方法基本上都取决于pH值或氢离子浓度的测量。这本书对化学家有价值。
A Critical Review of Equilibrium Data for Proton-and Metal Complexes of 1, 10-Phenanthroline, 2, 2'-Bipyridyl and Related Compounds is a compilation of acidity constants for the 1, 10-phenanthrolinium and 2, 2'-bipyridinium ions and their derivatives, as well as stability constants for metal complexes formed by the conjugate bases of these. These equilibrium data are critically examined. This monograph includes values determined in non-aqueous or mixed solvents, as well as those for a large number of"" mixed"" metal complexes incorporating these bases and a second ligand. The survey also contains known values for the enthalpies and entropies of formation for the proton-and metal-ion complexes. The compilation indicates the conditions under which the equilibrium constants apply and the methods by which they were determined. The acid-base properties of the compounds are represented by the acidity constant of the phenanthrolinium or bipyridinium ion expressed as a pK value. Nearly all the values listed were obtained either potentiometrically or spectrophotometrically, both of which depend fundamentally on measurements of pH or hydrogen-ion concentration. This book will be of value to chemists.