Merging Pd0/PdII Redox and PdII/PdII Non‐redox Catalytic Cycles for the Allylarylation of Electron‐Deficient Alkenes
Merging Pd0/PdII Redox and PdII/PdII Non‐redox Catalytic Cycles for the Allylarylation of Electron‐Deficient Alkenes
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合并 Pd0/PdII 氧化还原和 PdII/PdII 非氧化还原催化循环用于缺电子烯烃的烯丙基化
DOI：
10.1002/chem.202100075
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发表时间：
2021
期刊：
影响因子：
--
通讯作者：
Nakao Yoshiaki
中科院分区：
文献类型：
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作者：
Semba Kazuhiko;Ohta Naoki;Paulus Fritz;Ohata Masaki;Nakao Yoshiaki
已经开发出用芳基硼酸酯和烯丙基碳酸酯对缺电子烯烃进行烯丙基化。该方法允许从容易获得的起始材料中获得多种碳骨架。机理研究表明，该反应是通过基于 Pd0/PdII 氧化还原和 PdII/PdII 非氧化还原催化循环合并的协同催化实现的。
An allylarylation of electron‐deficient alkenes with aryl boronates and allylic carbonates has been developed. This method allows access to a wide variety of carbon skeletons from readily available starting materials. Mechanistic studies indicate that this reaction is enabled by a cooperative catalysis based on merging Pd0/PdIIredox and PdII/PdIInon‐redox catalytic cycles.