Sodium and barium cation-templated synthesis and cation-induced molecular pirouetting of a pyridine N-oxide containing [2]rotaxane
Sodium and barium cation-templated synthesis and cation-induced molecular pirouetting of a pyridine N-oxide containing [2]rotaxane
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DOI：
10.1039/c1cc11224d
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Beer, Paul D.
中科院分区：
文献类型：
--
作者：
Hancock, Laura M.;Beer, Paul D.
钠和钡金属阳离子模板已被用来构建一种新型的含有[2]轮烷的吡啶N-氧化物。添加和去除金属阳离子后，观察到大环组分围绕吡啶 N-氧化物轴进行旋转运动。
Sodium and barium metal cation templation has been used to construct a novel pyridine N-oxide containing [2]rotaxane. Upon addition and removal of metal cations, the macrocyclic component is observed to undergo a pirouetting motion around the pyridine N-oxide axle.