A new calix[5]arene-based container: selective extraction of higher fullerenes
A new calix[5]arene-based container: selective extraction of higher fullerenes
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DOI：
10.1021/ol061269b
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发表时间：
2006-08-03
期刊：
影响因子：
5.2
通讯作者：
Fukazawa, Yoshimasa
中科院分区：
文献类型：
--
作者：
Haino, Takeharu;Fukunaga, Chigusa;Fukazawa, Yoshimasa
新型双杯[5]芳烃成功地从富勒烯混合物中萃取高级富勒烯。双杯[5]芳烃的顺式异构体从富勒烯混合物中选择性地捕获高级富勒烯。超过100摄氏度的温度升高刺激其构象变化为反异构体，释放捕获的高级富勒烯。
A new double calix[5] arene successfully extracts higher fullerenes from fullerene mixtures. The syn isomer of the double calix[5] arene selectively captures higher fullerenes from fullerene mixtures. The elevation of the temperature more than 100 degrees C stimulates its conformational change to the anti isomer, bringing liberation of the captured higher fullerenes.