Helicenes Fused with Hexafluorocyclopentene (HFCP): Synthesis, Structure, and Properties
Helicenes Fused with Hexafluorocyclopentene (HFCP): Synthesis, Structure, and Properties
复制标题
螺烯与六氟环戊烯 (HFCP) 稠合：合成、结构和性能
DOI：
10.1002/ejoc.202000152
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发表时间：
2020
影响因子：
2.8
通讯作者：
Fukumoto
中科院分区：
文献类型：
--
作者：
Agou Tomohiro;Kohara Masaki;Tamura Yuuki;Yamada Keisuke;Shiitsuka Kazuki;Hosoya Takaaki;Mizuhata Yoshiyuki;Tokitoh Norihiro;Hayashi Yuki;Moronuki Yusuke;Ishii Akihiko;Tanaka Yusuke;Muranaka Atsuya;Uchiyama Masanobu;Yamada Shigeyuki;Konno Tsutomu;Fukumoto
利用二苯乙烯衍生物的氧化光环化反应（Mallory反应）合成了螺旋烯和六氟环戊烯（HFCP）。在新获得的氟化螺旋烯中，含有一个或三个HFCP单元的[7]螺旋烯通过X射线晶体学分析进行了结构表征。[9]螺旋烯与3个HFCP单元融合的尝试合成结果意外地形成了由[4]‐和[6]‐螺旋烯共享外周苯环组成的新型双螺旋烯。描述了新获得的HFCP取代螺旋烯的光学性质和手性分辨率。
Helicenes fused with hexafluorocyclopentene (HFCP) were synthesized by oxidative photocyclization of stilbene derivatives (the Mallory reaction). Of the newly‐obtained fluorinated helicenes, the [7]helicenes bearing one‐ or three‐HFCP units were structurally characterized by X‐ray crystallographic analysis. The attempted synthesis of [9]helicene fused with three HFCP units resulted in the unexpected formation of a novel double helicene consisting of [4]‐ and [6]‐helicenes sharing peripheral benzene rings. Optical properties and chiral resolutions of the newly obtained HFCP‐substituted helicenes are also described.