Supramolecular Click Assembly of a Fused Double-Stranded [MnII3] Dihelicate
Supramolecular Click Assembly of a Fused Double-Stranded [MnII3] Dihelicate
复制标题
稠合双链 [MnII3] 二螺旋的超分子点击组装
DOI:
--
复制
发表时间:
2007
期刊:
影响因子:
--
通讯作者:
J. Reedijk
中科院分区:
文献类型:
--
作者:
Jinkui Tang;J. Costa;G. Aromí;I. Mutikainen;U. Turpeinen;P. Gamez;J. Reedijk
A trinuclear MnII complex was obtained by reaction of manganese(II) perchlorate with the ligand 2-methoxy-6-(pyridine-2-ylhydrazonomethyl)phenol in methanol. The X-ray crystal structure of [Mn3L4](ClO4)2(H2O)2 (1) reveals that the “bent” chain of the MnII ions is assembled by a unique click-assembly of two double-stranded helicates. Magnetic susceptibility measurements show weak ferromagnetic interactions between the metal ions. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)