Main group functionalized polymers through ring-opening metathesis polymerization (ROMP)
Main group functionalized polymers through ring-opening metathesis polymerization (ROMP)
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DOI：
10.1016/j.polymer.2022.124739
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发表时间：
2022-03-18
期刊：
影响因子：
4.6
通讯作者：
Jakle, Frieder
中科院分区：
文献类型：
--
作者：
McQuade, James;Serrano, Mya I.;Jakle, Frieder
将主族元素引入聚合物中允许通过独特的分子几何形状、电子结构和基于主族元素的官能团的化学反应性来产生具有迄今无法实现的物理和化学性质的新功能材料。这些新材料的合成需要高度可控的聚合，其耐受不同的官能化单体。在这篇综述中，我们强调了开环易位聚合（ROMP）作为一种通用的和有利的方法产生新的主族元素功能化的杂化材料的最新进展。介绍了ROMP衍生的主基官能化聚合物在膜和聚电解质、树脂、复合材料、弹性体和其他工程材料、陶瓷前驱体和阻燃剂、聚合物配体和金属聚合物、聚合物催化剂和试剂以及光电材料中的独特应用。
The incorporation of main group elements into polymers allows for the generation of new functional materials with hitherto-unattainable physical and chemical properties through the unique molecular geometries, electronic structures, and chemical reactivities of main group element-based functional groups. The synthesis of these novel materials requires highly controllable polymerizations which are tolerant of diverse functionalized monomers. In this review, we highlight recent developments in ring-opening metathesis polymerization (ROMP) as a versatile and advantageous method for the generation of new main group element-functionalized hybrid materials. The unique applications of ROMP-derived main group-functionalized polymers in membranes and polyelectrolytes, resins, composites, elastomers, and other engineering materials, ceramic precursors and flame retardants, polymeric ligands and metallopolymers, polymeric catalysts and reagents, and optoelectronic materials are described.