Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes
Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes
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DOI：
10.1021/ja903574e
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发表时间：
2009-10-14
影响因子：
15
通讯作者：
Nozaki, Kyoko
中科院分区：
文献类型：
--
作者：
Tanaka, Ryo;Yamashita, Makoto;Nozaki, Kyoko
以一种新合成的异丙基取代的PNP-钳形三氢化铱配合物为催化剂，在氢氧化钾水溶液中进行了二氧化碳的催化加氢反应。甲酸钾的转化数高达3500000，转化频率为150000 h（-1），这两个值都是迄今为止报道的最高值。
Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium trihydride complex as a catalyst. Potassium formate was obtained with turnover numbers up to 3 500 000 and a turnover frequency of 150 000 h(-1), both of which are the highest values reported to date.