Catalytic enantioselective diboration, disilation and silaboration: new opportunities for asymmetric synthesis

Catalytic enantioselective diboration, disilation and silaboration: new opportunities for asymmetric synthesis
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DOI:
10.1039/b707779c
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发表时间:
2007-01-01
影响因子:
4.9
通讯作者:
Morken, James P.
Morken, James P.
中科院分区:
化学2区
文献类型:
--
作者:
Burks, Heather E.;Morken, James P.

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本文综述了近年来不饱和有机底物与二硼、硅基硼和二硅烷试剂催化不对称反应的研究进展。这些反应为前手性底物的功能化提供了新的途径,从而为不对称有机合成提供了新的策略。
This article summarizes recent developments in the area of catalytic enantioselective reactions of unsaturated organic substrates with diboron, silylboron, and disilane reagents. These reactions provide new routes to the functionalization of prochiral substrates and therefore offer new strategies in asymmetric organic synthesis.