Spontaneous alignment of self-assembled ABC triblock terpolymers for large-area nanolithography

Spontaneous alignment of self-assembled ABC triblock terpolymers for large-area nanolithography
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DOI:
10.1063/1.2975370
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发表时间:
2008-09-29
影响因子:
4
通讯作者:
Leighton, C.
Leighton, C.
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
Kubo, T.;Wang, R. F.;Leighton, C.

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提出了一种基于使用核-壳圆柱体形成ABC三嵌段三元共聚物制备大面积无机纳米结构阵列的通用方法。基本的垂直圆柱排列是通过使用低表面能 B 嵌段(聚异戊二烯)实现的,它驱动 A(聚苯乙烯)基质中圆柱 C 域(聚丙交酯)的自发垂直排列,消除了冗长的退火步骤、外部场排列程序或可能严重限制潜在应用的专门表面制备。 (C) 2008 年美国物理研究所。
A general method for preparation of large-area inorganic nanostructure arrays based on the use of core-shell cylinder forming ABC triblock terpolymers is presented. The essential perpendicular cylinder alignment is achieved by the use of a low surface energy B block (polyisoprene), which drives spontaneous perpendicular alignment of cylindrical C domains (polylactide) in a matrix of A (polystyrene), eliminating the lengthy anneal steps, external field alignment procedures, or specialized surface preparations that could severely restrict potential applications. (C) 2008 American Institute of Physics.