Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants.
Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants.
复制标题
DOI：
10.1039/d0cc06277d
复制
发表时间：
2020-10
影响因子：
4.9
通讯作者：
Ni Zhen;Jing Dong;Zhengguo Lin;Xiaoxia Li;Yingnan Chi;Changwen Hu
中科院分区：
文献类型：
--
作者：
Ni Zhen;Jing Dong;Zhengguo Lin;Xiaoxia Li;Yingnan Chi;Changwen Hu
本文报道了两个独立的钒铌酸盐H6Cs4Na5K7[V5Nb23O80]·28H2O（1）和H6Cs4Na5K8[V6Nb23O81]·34H2O（2）的合成和表征。这两种钒酸盐作为非均相催化剂能有效地促进芥子气模拟物的氧化去污。
We report the synthesis and characterization of two discrete vanadoniobates, H6Cs4Na5K7[V5Nb23O80]·28H2O (1) and H6Cs4Na5K8[V6Nb23O81]·34H2O (2), based on a brand new {Nb23} and a 5/6-nuclear polyoxovanadate cap. The two vanadoniobates as heterogeneous catalysts can effectively promote the oxidative decontamination of sulfur mustard simulants.