Stacking faults in BaTiO3 particles synthesized from organic precursor

Stacking faults in BaTiO3 particles synthesized from organic precursor
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由有机前驱体合成的 BaTiO3 颗粒中的堆垛层错

DOI:
10.1063/1.364333
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发表时间:
1997
影响因子:
3.2
通讯作者:
K. Takayanagi
K. Takayanagi
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Woo;E. Hamada;K. Takayanagi

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BaTiO3 powder has been synthesized by heat treating (BaTi) citrate polyester resins at 500 °C for 8 h. X-ray powder diffractometry (XRD) and Raman spectroscopy data suggest the presence of a high-temperature hexagonal phase at room temperature. However, high-resolution transmission electron microscopy indicates that the peaks that were ascribed to the above phase in the Raman and XRD spectra may originate from stacking faults in the particles. Our results disprove the existence of the high-temperature hexagonal BaTiO3 at room temperature.