Formation of a Thermally Stable, Porous Coordination Network via a Crystalline-to-Amorphous-to-Crystalline Phase Transition
Formation of a Thermally Stable, Porous Coordination Network via a Crystalline-to-Amorphous-to-Crystalline Phase Transition
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DOI：
10.1021/ja9005145
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发表时间：
2009-03-25
影响因子：
15
通讯作者：
Fujita, Makoto
中科院分区：
文献类型：
--
作者：
Ohara, Kazuaki;Marti-Rujas, Javier;Fujita, Makoto
一个多孔的配位网络，干净地获得后，晶体到无定形到结晶相转变，并明确地解决了晶体结构的从头算粉末X射线衍射。固态相变后，多孔结构是非常稳定的高达673 K，并能够重吸收各种客体分子，如芳香族溶剂和I-2。
A porous coordination network was cleanly obtained after a crystalline-to-amorphous-to-crystalline phase transition, and the crystal structure was unambiguously solved by ab initio powder X-ray diffraction. After the solid-state phase transition, the porous structure was remarkably stable up to 673 K and capable of reabsorbing various guest molecules, such as aromatic solvents and I-2.