Plasticizing of Naphthalene Single Crystals by Surface Active Organic Media

Plasticizing of Naphthalene Single Crystals by Surface Active Organic Media
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表面活性有机介质对萘单晶的塑化

DOI:
10.1080/00268947908084688
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发表时间:
1979
影响因子:
0.7
通讯作者:
E. D. Shchukin
E. D. Shchukin
中科院分区:
化学4区
文献类型:
--
作者:
V. Matvienko;N. Pertsov;E. D. Shchukin

文献摘要

被引文献

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摘要 利用蠕变技术作为位错运动的宏观反映,研究了表面活性介质对萘单晶流量的影响。蠕变测试的结果可以通过指数依赖性 e=eo exp(-(Uo, - γP)/KT] 很好地描述。根据该方程,计算了两个基础滑行系统和 3 个新发现的非基础系统的活化能 Uo 和活化体积 γ。滑行系统的类型、其方向和表面活性介质的存在显着影响 γ。表面活性介质显着增加 γ,有时增加两倍。
Abstract The effect of surface active media on the flowrate of naphtalene single crystals was studied with the help of creep technique as a macroscopic reflection of dislocations movement. The results of creep tests are well described by an exponential dependence e=eo exp(-(Uo, - γP)/KT]. According to this equation the activation energies Uo and activation volumes γ were calculated for two basal glide systems and for 3 newly discovered non-basal systems. The type of glide system, its orientation and the presence of surface active media markedly affect γ. Surface active media considerably increase γ, sometimes twofold.