NiII(TPA) as an efficient catalyst for alkane hydroxylation with m-CPBA
NiII(TPA) as an efficient catalyst for alkane hydroxylation with m-CPBA
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DOI：
10.1039/b608311k
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发表时间：
2006-01-01
影响因子：
4.9
通讯作者：
Itoh, Shinobu
中科院分区：
文献类型：
--
作者：
Nagataki, Takayuki;Tachi, Yoshimitsu;Itoh, Shinobu
一种简单的Ni-II（TPA）配合物[TPA =三（2-吡啶甲基）胺]已被证明是一种有效的周转催化剂，用于m-CPBA（m-chloroperbenzoic acid）的烷烃羟基化反应，其中NiO+（镍-氧）型活性氧物种的贡献被提出.
A simple Ni-II(TPA) complex [TPA = tris(2-pyridylmethyl) amine] has been demonstrated to act as an efficient turnover catalyst for alkane hydroxylation with m-CPBA (m-chloroperbenzoic acid), in which contribution of a NiO+ (nickel-oxo) type active oxygen species is suggested.