Triply Linked Porphyrinoids.
Triply Linked Porphyrinoids.
复制标题
三联卟啉。
作者：
Takayuki Tanaka;A. Osuka
三链卟啉阵列具有平面结构、远红移吸收带、多电荷存储能力和高电导率等特点。最近，卟啉带变体如卟啉-膨胀的卟啉杂化带、卟啉拱形带、可咯带和亚卟啉带已被探索为新型π-共轭材料。这些新的分子表现出电子和结构特性，由于直接的三键。本文首先介绍了卟啉带和卟啉带的基本性质。然后，重点放在最近开发的卟啉带变体的合成，结构和独特的性能上。
Triply linked porphyrin arrays, so called porphyrin tapes, are intriguing molecules in terms of their planar structures, far red-shifted absorption bands, multi-charge storage abilities, and high conductivities. Recently, porphyrin tape variants such as porphyrin-expanded porphyrin hybrid tapes, porphyrin arch-tapes, corrole tapes, and a subporphyrin tape have been explored as novel π-conjugated materials. These new molecules exhibit electronic and structural characteristics owing to direct triple linkages. This Minireview first discusses the fundamental properties of the parent porphyrin tapes and the peripherally functionalized porphyrin tapes. Then, a focus has been placed on the syntheses, structures, and unique properties of the recently explored porphyrin tape variants.
影响因子：
62.1
作者：
Teo RD;Hwang JY;Termini J;Gross Z;Gray HB
通讯作者：
Gray HB
影响因子：
15
作者：
Davis, Nicola K. S.;Thompson, Amber L.;Anderson, Harry L.
通讯作者：
Anderson, Harry L.