Cellulose Hydrolysis by a New Porous Coordination Polymer Decorated with Sulfonic Acid Functional Groups
Cellulose Hydrolysis by a New Porous Coordination Polymer Decorated with Sulfonic Acid Functional Groups
复制标题
DOI：
10.1002/adma.201101356
复制
发表时间：
2011-08-02
影响因子：
29.4
通讯作者：
Kitagawa, Susumu
中科院分区：
文献类型：
--
作者：
Akiyama, George;Matsuda, Ryotaro;Kitagawa, Susumu
合成了一种基于MIL-101的含磺酸基的多孔配位聚合物（PCP）。磺酸基暴露在孔表面上，并作为强布朗斯台德酸位点。这种固体酸PCP催化水解纤维素为单糖和二糖，并在催化反应中显示出高耐久性。
A MIL-101-based porous coordination polymer (PCP) containing sulfonic acid groups is synthesized. The sulfonic groups are exposed on the pore surface and act as strong Bronsted acid sites. This solid acid PCP catalytically hydrolyzes cellulose into mono- and disaccharides and shows high durability in the catalytic reaction.