Electrochemical promotion of catalytic reactions
Electrochemical promotion of catalytic reactions
复制标题
DOI：
10.1007/s40828-018-0077-9
复制
发表时间：
2010-05
期刊：
影响因子：
2.4
通讯作者：
R. Imbihl
中科院分区：
文献类型：
--
作者：
R. Imbihl
通过使用与固体电解质连接的多孔金属电极，电化学促进非均相催化反应（EPOC）成为可能。 EPOC 效应已在 100 多个反应体系中得到证实。表面科学研究表明，EPOC 效应的物理基础在于电化学诱导的传输离子物质溢出到金属电极表面。本报告总结了对 EPOC 效应机制的理解所取得的进展。
An electrochemical promotion of heterogeneously catalyzed reactions (EPOC) became possible through the use of porous metal electrodes interfaced to a solid electrolyte. The EPOC effect has been demonstrated for more than 100 reaction systems. Surface science investigations showed that the physical basis for the EPOC effect lies in the electrochemically induced spillover of the transported ionic species onto the surface of the metal electrodes. This report summarizes the progress which has been achieved in the mechanistic understanding of the EPOC effect.