4,4,6-trimethyl-2-vinyl-1,3,2-dioxaborinane: An efficient and selective 2-carbon building block for vinylboronate Suzuki-Miyaura coupling reactions
4,4,6-trimethyl-2-vinyl-1,3,2-dioxaborinane: An efficient and selective 2-carbon building block for vinylboronate Suzuki-Miyaura coupling reactions
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DOI：
10.1055/s-2005-862354
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发表时间：
2005-02-16
期刊：
影响因子：
2
通讯作者：
Whiting, A
中科院分区：
文献类型：
--
作者：
Lightfoot, AP;Twiddle, SJR;Whiting, A
利用钯催化合成功能化的苯乙烯和二烯的一种非常简单和有效的偶联过程，展示了如何使用4，4，6-三甲基-2-乙烯-1，3，2-二恶硼杂环与一系列卤化物底物选择性地进行Suzuki-Miyaura偶联反应。
An extremely simple and efficient palladium-catalyzed coupling procedure for the synthesis of functionalized styrenes and dienes is utilized to demonstrate how 4,4,6-trimethyl-2-vinyl-1,3,2-dioxaborinane can be employed to selectively undergo Suzuki-Miyaura coupling with a range of halide substrates.