A new selective chromogenic and fluorogenic sensor for citrate ion
A new selective chromogenic and fluorogenic sensor for citrate ion
复制标题
DOI：
10.1016/j.snb.2012.07.030
复制
发表时间：
2012-11-01
影响因子：
8.4
通讯作者：
Yen, Yao-Pin
中科院分区：
文献类型：
--
作者：
Liu, Zhao-Hong;Devaraj, Soosai;Yen, Yao-Pin
开发了一种新受体 1，并研究了其对各种二羧酸根和三羧酸根阴离子的显色和荧光行为。受体 1 仅对柠檬酸根阴离子表现出响应，并且还通过水溶液中不同的颜色变化（DMSO/H2O = 4/1）区分柠檬酸根阴离子和其他阴离子。此外，受体1还表现出明显的柠檬酸盐诱导的荧光增强。柠檬酸根阴离子的检测限确定为(0.18+/-0.01μM)。因此，受体1可以用作用于测定柠檬酸根离子的比色和荧光传感器。 (C) 2012 Elsevier B.V. 保留所有权利。
A new receptor 1 was developed, and its chromogenic and fluorogenic behaviors toward various di- and tricarboxylate anions were investigated. Receptor 1 shows response exclusively toward citrate anion and also distinguishes citrate anion from other anions by different color change in aqueous solution (DMSO/H2O = 4/1). In addition, the receptor 1 also exhibits a pronounced citrate-induced fluorescence enhancement. The detection limit for the citrate anion was determined as (0.18 +/- 0.01 mu M). Thus, the receptor 1 can be used as a colorimetric and fluorescent sensor for the determination of citrate ion. (C) 2012 Elsevier B.V. All rights reserved.